·¢²¼Ê±¼ä : ÐÇÆÚ¶þ ÎÄÕ¡¶Óлú»¯Ñ§¡·Ï°Ìâ´ð°¸£¨¸ßºè±öµÚËİ棩 - ͼÎĸüÐÂÍê±Ï¿ªÊ¼ÔĶÁ
2,2,5-Èý¼×»ù-3-¼ºÈ²
(Ò») ÓÃZ,E-±ê¼Ç·¨ÃüÃûÏÂÁи÷»¯ºÏÎ
Cl3-Ò춡»ù-4-¼ºÏ©-1-Ȳ
(1) ¡ý
C=CCH3ClFCH3¡ü (2) ¡ü
C=CCH3CHH2C3Cl¡ü
(E)-2,3-¶þÂÈ-2-¶¡Ï©
FBrC=CI(Z)- 2-¼×»ù-1-·ú-1-ÂÈ-1-¶¡Ï©
HCHCHCH223C=C(4) ¡üCHCH(CH)332(3) ¡ü
Cl¡ü
¡ü
(Z)-3-Òì»ù-2-¼ºÏ©
(Z)-1-·ú-1-ÂÈ-2-äå-2-µâÒÒÏ©
(¶þ) д³öÏÂÁл¯ºÏÎïµÄ¹¹Ôìʽ£¬¼ì²éÆäÃüÃûÊÇ·ñÕýÈ·£¬ÈçÓдíÎóÓèÒÔ
¸ÄÕý£¬²¢Ð´³öÕýÈ·µÄϵͳÃû³Æ¡£ (1) ˳-2-¼×»ù-3-ÎìÏ©
CH3CH3CH54321(2) ·´-1-¶¡Ï©
CH=CHCHCH223
CH3HC=CH
˳-4-¼×»ù-3-ÎìÏ© (3) 1-äåÒ춡ϩ
CH3C=CHBr
3211-¶¡Ï© (ÎÞ˳·´Òì¹¹) (4) (E)-3-ÒÒ»ù-3-ÎìÏ©
CHH2C3CH3 CHH=CHCH3C2C3543212-¼×»ù-1-äå±ûÏ©
(Èý) Íê³ÉÏÂÁз´Ó¦Ê½£º
3-ÒÒ»ù-2-ÎìÏ© (ÎÞ˳·´Òì
¹¹)
½â£ººìÉ«À¨ºÅÖÐΪ¸÷СÌâËùÒªÇóÌî³äµÄÄÚÈÝ¡£
CH3HCHC=CH + HCl(1) C322FCH=CH + HCl32(2) C????CH3CHCHCCH323
ClCFCHCHCl 322CH)C=CH + Br3222(3) (NaClË®ÈÜÒº (CH)CCHCl(CH)CCHOH(CH)CCHBr+322322+322Bra½âÊÍ£º(CH)CCH322Br(1) 1/2(BH)3222Br--Br or Cl or HO2Br
b
a ·½Ê½¿Õ¼äÕϰС£¬²úÎïÕ¼ÓÅHOHHCHCCHCHCHCHCHO(4) C 32322-CHCHCCH(2) HO , OH32(ÅðÇ⻯·´Ó¦µÄÌص㣺˳¼Ó¡¢·´Âí¡¢²»ÖØÅÅ)
OH(5)
CH+ Cl + HO322CH3(1) 1/2(BH)32-(2) HO , OH22CH3Cl+CH3ClOHCH3
(6)
CH3OH CH3(ÅðÇ⻯·´Ó¦µÄÌص㣺˳¼Ó¡¢·´Âí¡¢²»ÖØÅÅ)
CH3Cl2500 CoHClC3HBrHClC3CHBr 2(B)(7)
CH2CH2ROOR(A)Br(CH)CHCCHCH)CHCCH(8) (323 32¹ýÁ¿BrHgSO4(9) C HCHCCH + HOCHCHCCH322H323SO24HBrO(10) CH=CHCH3KMnO4?COOH + CHCOOH 3O(11)
(1) O3(2) HO , Zn2
O(12) (13)
+ Br2300 CoBr
Br+ NaCCH
HCH65CC CH65OHHCH65CHCOH33C=C(14)
CH65Hi) (Îå) Óüò±ãµÄ»¯Ñ§·½·¨¼ø±ðÏÂÁи÷×黯ºÏÎ
A)(1) ((A))½â£º(B(C)(B)(C)
Br2CCl4xMnOÍÊÉ«K4ÍÊÉ«
ÍÊÉ«xCH3(2) ((CH)C=CHCHA)B)CH(CH)CCH(C)2523(324(A)½â£º(B)(C)g(NH)NOÍÊÉ«A323ÍÊÉ«
Br2CCl4xÒø¾µ
xHii) (Áù) ÔÚÏÂÁи÷×黯ºÏÎïÖУ¬ÄÄÒ»¸ö±È½ÏÎȶ¨£¿ÎªÊ²Ã´£¿
HH(1) (A)
CH3C=CCH(CH3)2CH3 £¬ (B)
CH3C=CCH(CH3)2H
½â£º(B)Öм׻ùÓëÒì±û»ùµÄ¿Õ¼äÓµ¼·³Ì¶È½ÏС£¬¸ü¼ÓÎȶ¨¡£ (2) (A)
£¬ (B)
CH3
½â£º(A)Öм׻ùÓë̼-̼˫¼üÓнϺõĦÒ-¦Ð³¬¹²é¹Ê(A)±È½ÏÎȶ¨¡£
(3) (A) £¬ (B) £¬ (C)
½â£º(C)µÄ»·ÕÅÁ¦½ÏС£¬½ÏÎȶ¨¡£ (4) (A)
£¬ (B)
½â£º(A)µÄ»·ÕÅÁ¦½ÏС£¬½ÏÎȶ¨¡£ (5) (A) (6) (A)
£¬ (B)
£¬ (C)
CH2
½â£º(C)×îÎȶ¨¡£
CH3 £¬ (B)
½â£º(A)µÄ»·ÕÅÁ¦ºÜ´ó£¬ËùÒÔ(B)½ÏÎȶ¨¡£
iii) (Æß) ½«ÏÂÁи÷×é»îÐÔÖмäÌå°´Îȶ¨ÐÔÓÉ´óµ½Ð¡ÅÅÁгÉÐò£º
C)(CH)CCHCHCH(B)ClCCHCHA)333333((1) (
(B)(CH)CCHCH(CH)CHCHCHA)(CH)CHCHCH(C)32233233222(2) (
½â£º(1)C£¾A£¾B (2)B£¾C£¾A
iv) (°Ë) ÏÂÁеÚÒ»¸ö̼ÕýÀë×Ó¾ùÇãÏòÓÚÖØÅųɸüÎȶ¨µÄ̼ÕýÀë
×Ó£¬ÊÔд³öÆäÖØÅźó̼ÕýÀë×ӵĽṹ¡£
(1) CH3CH2CH2 (2) (CH)2CHCHCH33 (3) (CHCHCH3)3C3 (4) ½â£ºÌâ¸ø̼ÕýÀë×ӿɾÖØÅÅÐγÉÏÂÁÐ̼ÕýÀë×Ó£º
(1) CH3CHCH3 (2) (CH)2CCHCH323 (3) (CH)2CCH(CH)2 (4) 33CH3 CH3
v) (¾Å) ÔÚ¾Û±ûÏ©Éú²úÖУ¬³£ÓüºÍé»ò¸ýÍé×÷ÈܼÁ£¬µ«ÒªÇóÈÜ
¼ÁÖв»ÄÜÓв»±¥ºÍÌþ¡£ÈçºÎ¼ìÑéÈܼÁÖÐÓÐÎÞ²»±¥ºÍÌþÔÓÖÊ£¿ÈôÓУ¬ÈçºÎ³ýÈ¥£¿
½â£º¿ÉÓÃBr2/CCl4»òÕßKMnO4/H2O¼ìÑéÈܼÁÖÐÓÐÎÞ²»±¥ºÍÌþÔÓÖÊ¡£ ÈôÓУ¬¿ÉÓÃŨÁòËáÏ´È¥²»±¥ºÍÌþ¡£